History Of Man Made Diamonds

Henri Moissan (1852-1907) received the Nobel Prize inDiamonds and Tairus all utilize the HPHT method of
Chemistry in 1906. In 1892 theorized that byproducing gem quality man made diamonds. Clear or
crystallizing carbon with pressure and heat fromWhite diamonds must be produced in an environment
molten iron he could make diamonds. The then setthat is free of impurities like nitrogen and boron which
out to prove his theory by designing and building anmakes them very difficult and costly to produce.
electric-arc furnace. He subsequently was able toMost diamonds created by the HPHT method will
product several tiny stones that had the samecontain some color. Yellow or orange tint occurs
properties as mined diamonds. Thus the start of thewhen nitrogen atoms replace 5 or more carbon
man made diamond race was born.atoms out of each 10,000 atoms. At a level of one
The experiment was successfully repeated by Ruffinor a few boron atoms for every million-carbon atom
in 1917 and again by Dr Willard Hershey in 1926. Theis replaced, an attractive blue color results.
diamond that was created by Dr Willard Hershey isThe second method used to produce gem quality
on display in Kansas at the McPherson Museum.diamonds is called Chemical Vapor Deposition (CVD).
Despite the earlier success, the followingWhen pure carbon and hydrogen is heated to about
experimenters had great difficulty in reproducing the1,8000 degrees Fahrenheit a plasma cloud is formed.
required temperatures and pressures needed by theAs the plasma cools carbon will rain out of the
process and some of the experimenters even lostmixture and carbon atoms will be deposited on wafer
their lives to explosions.seeds. The wafers will grow at about 1/2 a millimeter
In 1941 General Electric was able to produce a onea day. The ability to control the injection of impurties
carat diamond but of very poor quality. It was notallows a greater measure of control in the final
until 1954 that General Electric was able to producediamond composition than the HTHP method. Apollo
commercially synthesis diamonds of a size and qualityDiamond uses the CVD method of producing the
to be used in the industrial abrasives market. Todaylarger and more expensive man made diamonds.
over 600 metric tons of commercially producedMan-made diamonds are very difficult to distinguish
diamonds are produced for the industrial abrasivesfrom natural ones. A trained jeweler could tell the
market and about 26 metric tons of mined diamondsdifference if he could detect the different growth
are produced for gemstone market yearly.patterns and the lack of inclusions. Inclusions are the
Today there are two methods used to produce gemtiny bits of material that are usually imbedded in a
quality diamonds. The first is the High Pressure Highnatural diamond and are considered a flaw. The ability
Temperature (HPHT). If pure carbon in put underto be able to control the amount and type of
pressures of 50,000 atmospheres and temperaturesinclusion is vital to the ability of the man made
between 1100, and 1400 degrees Celsius willdiamond to be used in semiconductor applications
reproduce the environment that creates diamondswhich in turn will lead to the next generation of
inside the Earths core.computer chips.
Companies like Gemesis, New Age Diamonds, Adia